Slash fire hazard analysis on the Siskiyou National Forest

Potential increase in fire hazard as a result of timber harvesting is a concern of forest managers throughout the United States. Treating fuels can help reduce unacceptable fire hazards. To evaluate alternative fuel treatments, managers need to know their effects on fire hazard. A decision analysis approach to estimating fire hazard in terms of expected burned area was applied to a watershed in the Siskiyou National Forest (Oregon). Three treatment alternatives (do nothing and two levels of yarding unmerchantable material) were evaluated, and the effects of the treatments were projected over a 90-yr period. Initially, the effects of applying a treatment are small. After 50 years of treatment, the most intense alternative can be expected to show almost a 50% reduction in burned area compared to no treatment. The procedure also estimates burned are by fire size and fire intensity classes. Managers may find this useful for estimating expected fire effects associated with a particular fuel treatment regime.     

Recent Electrostatic Precipitator Experience with Ammonia Conditioning of Power Boiler Flue Gases

Motivated by heightened recent interest, Koppers Co. has been experimenting with ammonia conditioning of power boiler flue gases for the purpose of improving the precipitability of the emitted fly ash. Chemical reactions resulting from ammonia injection are postulated. Measurements on three pulverized coal and two cyclone fired boilers, all of which emit acidic ash, are described. In all five cases, considerable but varying, increase in precipitator power input and collection efficiency resulted when gaseous ammonia in the amount of 1 5 ppm was injected between the economizer and air preheater. The conditioned fly ash showed decreased acidity and inconsistent change in electrical resistivity. Unless air heater temperatures were unusually high (>400°F), tendency of the air heater to plug was an additional, but unwanted, result. At one station with high air heater outlet temperature ammonia injection has been adopted as a permanent solution to community pressure for reduction of stack discharge. Ammonia injection downstream of the air heater produced no effect. Future plans are presented to continue the program beyond results described here.     

Objective Evaluation of Emergency Plans for Oxidant Control

Emergency plans for oxidant controls provide the basis for taking preventive action to protect public health. Historic oxidant data (1970 to Sept. 1974) from the South Coast Air Basin (SCAB), were evaluated to assess episode characteristics in an area where emergency strategies are most likely to be enforced. These findings, together with an objective study of a test case episode (June 1974) using a photochemical air quality simulation model, suggest that the currently conceived emergency plans for oxidant control are unlikely to be effective. It is concluded that, because of the chemical and mefeorofogfcal complexities of the episodes, they are extremely difficult both to predict and concurrently to control over their short-lived duration.     

Chemical composition of the slippery epicuticular wax blooms on Macaranga (Euphorbiaceae) ant-plants

Summary. The stems of many Macaranga ant-plants (Euphorbiaceae) are covered by epicuticular wax crystals rendering the surface very slippery for most insects. These wax blooms act as selective barriers protecting the symbiotic ant partners, which are specialized “wax-runners”, against the competition of other ants. Glaucous stems occur almost exclusively among the ant-plants of the genus Macaranga (). We analyzed the cuticular lipids of 16 Macaranga species by GC-MS and investigated the wax crystal morphology using SEM. Presence of crystalline wax blooms was strongly correlated with high concentrations (52%–88%) of triterpenoids. In contrast epicuticular waxes of glossy Macaranga surfaces contained only 0% to 36% of these dominant components. Therefore we conclude that triterpenoids are responsible for the formation of the thread-like Macaranga wax crystals. In all Macaranga ant-plants investigated, the principal components were epitaraxerol and taraxerone accompanied by smaller portions of taraxerol, β-amyrin and friedelin. Only in the case of the non-myrmecophytic M. tanarius did β-amyrin predominate. Moreover, we found that only in M. tanarius, the dense wax crystal lacework is torn into large mosaic-like pieces in the course of secondary stem diameter growth. Both chemical and macroscopic differences may contribute to a reduced slipperiness of M. tanarius stems and appear to be functionally important. The distribution of wax crystals and their composition amongst different sections of the genus suggests that glaucousness is a polyphyletic character within Macaranga. Received 7 October 1999; accepted 3 December 1999     

Kriterien für eine ökologisch nachhaltige Stoff-und Gentechnikpolitik

Based on the precautionary principles and the functional model of the environment, the meaning of the criterion of sustainability is explained and applied on organic chemicals and genetically modified organisms (GMOs). It is shown that the criterion permits the sustainability of an operationalization of the precautionary principle as interpreted strictly and the ecological component records the sustainability for the respective areas of environmental problems. Using examples from the field of chemistry, it has been demonstrated that problems have arisen through the substituted substances which are recognized as being ecologically harmful, since the sustainability was not applied as the central criterion for the environmental evaluation of organic materials. The conventions on ‘Persistent Organic Pollutants’ (POPs) which have been agreed upon provide a chance to revive the research on the sustainability of organic chemicals. Similar findings are seen for the GMOs, whose ecosystemic risks should not merely be defined based upon their human toxicological and already recognized ecological aspects.     

Efficiency of Reovirus Concentration from Water with Positively Charged Filters

This study examined the efficacy of reovirus concentration from large volumes of water using two positively charged filters: Zeta Plus 1MDS and NanoCeram. The results indicated that an average of 61 and 81% of input reoviruses were effectively recovered, respectively, from recycled water and tap water using NanoCeram filtration.     

Natural zeolites

Zeolites, a suite of porous, fine-grained minerals commonly found in certain near-surface, sedimentary rocks, have special physical and chemical properties that could make them valuable to farmers in developing countries. Zeolites have been used to improve soil fertility; develop slow-release fertilizers; improve animal waste disposal; and improve animal health. To date most research on zeolite deposits and their various applications has been undertaken by the industrialized nations. Some zeolite deposits, however, also exist in developing countries and the likelihood of the existence of additional deposits in those countries is high. However, thorough assessment of the mineralogy, geology, and various agricultural uses is still needed. Strengthening developing countries' geological surveys in non-metallic mineral exploration and assessment will improve the likelihood that the use of zeolites will reach their full potential in developing country agriculture.     

Effect of biogas generation on radon emissions from landfills receiving radium-bearing waste from shale gas development

Dramatic increases in the development of oil and natural gas from shale formations will result in large quantities of drill cuttings, flowback water, and produced water. These organic-rich shale gas formations often contain elevated concentrations of naturally occurring radioactive materials (NORM), such as uranium, thorium, and radium. Production of oil and gas from these formations will also lead to the development of technologically enhanced NORM (TENORM) in production equipment. Disposal of these potentially radium-bearing materials in municipal solid waste (MSW) landfills could release radon to the atmosphere. Risk analyses of disposal of radium-bearing TENORM in MSW landfills sponsored by the Department of Energy did not consider the effect of landfill gas (LFG) generation or LFG control systems on radon emissions. Simulation of radon emissions from landfills with LFG generation indicates that LFG generation can significantly increase radon emissions relative to emissions without LFG generation, where the radon emissions are largely controlled by vapor-phase diffusion. Although the operation of LFG control systems at landfills with radon source materials can result in point-source atmospheric radon plumes, the LFG control systems tend to reduce overall radon emissions by reducing advective gas flow through the landfill surface, and increasing the radon residence time in the subsurface, thus allowing more time for radon to decay. In some of the disposal scenarios considered, the radon flux from the landfill and off-site atmospheric activities exceed levels that would be allowed for radon emissions from uranium mill tailings.

Implications: Increased development of hydrocarbons from organic-rich shale formations has raised public concern that wastes from these activities containing naturally occurring radioactive materials, particularly radium, may be disposed in municipal solid waste landfills and endanger public health by releasing radon to the atmosphere. This paper analyses the processes by which radon may be emitted from a landfill to the atmosphere. The analyses indicate that landfill gas generation can significantly increase radon emissions, but that the actual level of radon emissions depend on the place of the waste, construction of the landfill cover, and nature of the landfill gas control system.     

ESTROM,Environmental Science and Technology in Romania—programme overview

Environmental Science and Pollution Research -     

The historical record of PCB and PCDD/F deposition at Greifensee, a lake of the Swiss plateau, between 1848 and 1999

Dated sediment cores provide an excellent way to investigate the historical input of persistent organic pollutants into the environment and to identify possible sources of pollution. The vertical distribution of polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDD/F) and polychlorinated biphenyls (PCB) was investigated in a sediment core from Greifensee to elucidate the historical trends of PCDD/F and PCB inputs between 1848 and 1999. Concentrations of PCB and PCDD/F increased by more than one order of magnitude between 1930 and 1960. PCB and PCDD/F concentrations were 5700 ng/kg dry weight (dw) and 160 ng/kg dw, respectively, in sediments originating from the late 1930s and reached a maximum of 130,000 ng/kg dw and 2400 ng/kg dw, respectively, in the early 1960s. From 1960 on, concentrations decreased to the 1930s level by the mid 1980s. A remarkable shift in the PCDD/F pattern was observed after the early 1940s. Before 1940, the PCDD/F pattern was PCDF dominated (ratio of PCDD to PCDF=0.41+/-0.11), while the PCDD started to be the major species after the early 1940s (ratio of PCDD to PCDF=1.46+/-0.38). The temporal trends of PCB and PCDD/F correlate surprisingly well with each other. This might be due to the coincidence of two factors. The introduction of PCB on the market in the 1930s resulted in emissions due to the widespread use of these industrial chemicals. In the same time period, waste incineration became an increasingly popular way to get rid of garbage, boosting the PCDD/F emissions significantly. The rapid decline of PCDD/F and PCB concentrations in the sediment starting in the early 1960s reflects the result of better emission control techniques in thermal processes and the improvement of waste water treatment in the catchment of Greifensee.